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After a few minutes, the solution will effervesce vigorously and fine, pink copper particles will begin to form and become visible to the naked eye Small bubbles of flammable hydrogen gas will also evolve from the solution, and these must be rapidly removed by appropriate exhausts Usually within about one hour, the solution will turn clear and copper will precipitate from the solution These fines will eventually settle to the bottom of the batch tank and the copper fines should be removed as soon as the reaction has been completed Otherwise the copper fines may reoxidize and dissolve back into solution More NaBH4 will then be necessary to remove the copper After the copper fines have been removed, hydrogen peroxide (H2O2) can be added to the clear solution to oxidize any excess formaldehyde to the less toxic formic acid.

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In relativity it is often necessary to change from one coordinate system to another, or from one frame to another. A transformation of this kind is implemented with a transformation matrix that we denote by a b . The placement of the indices and where we put the prime notation will depend on the particular transformation. In a coordinate transformation, the components of a b are formed by taking the partial derivative of one coordinate with respect to the other. More speci cally,

This process can be used for other metal-bearing waste streams besides electroless copper However, it is typically not a cost-effective means of treating nonchelated waste..

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Aqueous and Semiaqueous Photoresist Stripping Bath Treatment A significant volume of waste produced from PCB factory is from the stripping of resists. Resist stripping machines can utilize on-line or off-line equipment to remove semisolid photoresists on a continuous basis from the operating bath. Removing the suspended solids within the solution provides a longer life and more efficient usage. In any case, there will be times when the bath becomes spent and must be dumped. Waste from this process should be segregated for treatment so that the sludge produced can be classified as nonhazardous. In addition, good engineering practice dictates that spent photoresist stripping baths not enter a continuous precipitation system since organic photopolymers may not always settle in a clarifier. Under some conditions (at certain temperatures or with certain organics), stratification of the organic material in the clarifier can occur. As a result, the organic solids can float and any metal hydroxide particles nearby may become attached to the floating material. The treatment procedure for this waste uses chemical precipitation (caused by lowering the pH) and filtration (to remove the photoresist and residual metals). The treated wastes can be slowly discharged into the existing final pH adjustment tank. The specific treatment procedure follows. The untreated pH of this waste is approximately 12.0 pH units. Sulfuric acid is slowly added to lower the pH to about 9.0. After a stable pH is achieved, the pH will be lowered to about 6.0 by the addition of acidic proprietary chemicals available at the time of this writing. At this low pH, the dissolved resist will precipitate out of solution and the solids formed can be removed by pumping the waste through a filter press.

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The Code 39 error is one of several Device Manager error codes . In most cases, a Code 39 error is caused by either a missing driver for that particular piece of hardware or by a Windows Registry issue. While less common, a Code 39 error can also be caused by a corrupt driver or driver related file.
The Code 39 error is one of several Device Manager error codes . In most cases, a Code 39 error is caused by either a missing driver for that particular piece of hardware or by a Windows Registry issue. While less common, a Code 39 error can also be caused by a corrupt driver or driver related file.

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Definition Chemical treatment of wastes involves the addition of chemicals to precipitate metals out of solution. This results in a sludge which must be disposed of. The sludge is then typically sent to a reclaimer for recovery of the metals or licensed disposal site. The latter option is becoming increasingly difficult and expensive. It should be avoided due to the unknown risks associated with the landfill of hazardous wastes. Chemical treatment of wastes should be utilized only when pollution prevention or recycling is not technically or economically feasible.

Treatment Process Nonchelated metal rinses and dumps are typically treated in a two-stage process. In the first stage, rough pH control is accomplished with the addition of caustic soda and sulfuric acid. In the second stage, the pH is elevated with caustic to precipitate the metals in the hydoxide form. Lime has been used in this step in the past, but its use has been discouraged since it increases the sludge volume significantly. Alternatively, the metals can be precipitated as in the sulfide form with the addition of FeS at pH 9. This process is more difficult to control and presents a potential hazard due to the possible evolution of H2S. However, the lower solubility of the metal sulfides provides an advantage where discharge limits are more stringent. Chelated metal rinses and dumps such as those from the electroless copper process provide more challenge in chemical treatment since the chelating agents bind the metals and keep them in solution. This problem is often addressed by the addition of ferrous sulfate to break down the chelated metal complexes, allowing the metal to precipitate as the hydroxide. It is often necessary to add large quantities of this reagent such that the ratio of iron to copper is 8:1. The disadvantage of this method is that iron will precipitate out as well, thus significantly increasing the volume of sludge produced. Regardless of the specific treatment chemistry used, there are common components to all chemical treatment systems.

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